The 33-year-old actress – who gave birth to twins Knox and Vivienne earlier this month – is said to be in final negotiations with studio bosses to play the feline villain who first appeared in the Batman comics.
It is not clear whether she would play the role in the current Batman film series, starring Christian Bale as the caped crusader, or in a spin-off film as Halle Berry did in 2004’s Catwoman.
Actress Julie Newmar, who played Catwoman in the Batman TV series from 1966 to 1967, has given her blessing for Jolie to play the part.
“Angelina would own the part,” Newmar, now 74, said.
“My industry friends tell me she has already made enquiries about the role. I can understand how it would pique her interest. Catwoman is Batman’s one true love.
“She is tremendously popular with women because she’s both a heroine and a villainess.”
Other actresses to take on the role of Catwoman include Michelle Pfeiffer in 1992 movie Batman Returns, and Eartha Kitt who took over from Newmar in the TV series.
Jolie was recently tipped to be starring in The Thomas Crown Affair 2 alongside Pierce Brosnan and has reportedly been ordered by studio bosses to put on weight for the role.